iClarified - iPhone Tutorials
http://www.iclarified.com
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iClarified has the largest collection of step-by-step tutorials for the iPhone. All of their tutorials are great quality, and include step-by-step screenshots as well as a video guide!
They cover a whole range of know-how with their tutorials, including iPhone unlocking, jailbreaking and hacking. How to use your iPhone as a modem, how to customise your iPhone with custom made themes and wallpapers and so much more.
If you want to know how to do anything with your iPhone, then iClarified should be your first port of call.